Tetrahedron p. 5853 - 5864 (1987)
Update date:2022-08-11
Topics:
Sergeev, G. B.
Smirnov, V. V.
Rostovshchikova, T. N.
Komissarovan N. V.
Indoleva, Ye. V.
Complexes and reactions of 2-methylbutene-2 with hydrohalogen (HCl, HBr) have been studied in solid phase at 80-150 deg K.It has been found that 2-methylbutene-2 forms with HX complexes of 1:1 and 1:2 composition.Hydrohalogenation proceeds via the rearrangement of complex 2HX*C5H10 into complex of addition product with HX.Kinetic equation depends on the reagents ratio.In excess of HX (1
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