Journal of Physical Chemistry p. 8021 - 8025 (1989)
Update date:2022-08-10
Topics:
Cartland, Harry E.
Pimentel, George C.
The reaction of Hg atoms in the 3P state with the ethyl halides is studied in krypton matrix.The primary products result from molecular elimination, though the behavior of ethyl fluoride is different from that of ethyl chloride and bromide in that H2 elimination is observed exclusively rather than the hydrogen halide elimination that predominates for the other ethyl halides.Some insertion of Hg into C-Cl and C-Br bonds occurs, a process absent in the gas-phase photochemistry.
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