Tetrahedron Letters p. 1063 - 1066 (1987)
Update date:2022-08-12
Topics:
Negri, David P.
Kishi, Yoshito
A total synthesis of (-)-A23187 (calcimycin) was accomplished by a convergent approach.The key step of synthesis was the stereospecific cyclization of the β-hydroxy ketone into the spiroketal under basic conditions.
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(2021)
