Silaethene in Pyrolysis of Spirosilafluorene>

DOI: 10.1246/bcsj.60.2263

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2263 - 2264 (1987)

Update date:2022-08-11

Topics:

Authors:

Terunuma, Daiyo

Nakamura, Makoto

Miyazawa, Eiji

Nohira, Hiroyuki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.60.2263

A new silaspiro compound, i.e., spirosilafluorene>(1) was synthesized in 75percent yield.It was found that the pyrolysis of 1 at 650 deg C under a reduced pressure gave a head-to-tail silaethene dimer in 15percent yield.Copyrolysis of 1 in the presence of benzophenone gave 1,1-diphenylethene and a siloxane oligomer in 50 and 30percent yield, respectively.

Full text of DOI:10.1246/bcsj.60.2263

Products guided by the article

Product name:1,1-Diphenylethylene

Cas No:530-48-3

R&D Labs maybe for 530-48-3

Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Wuhan Sunrise Pharmaceutical Technology Co., Ltd

Contact:+86-27-83314682

Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
Zhenjiang Huayu I/E Co.,LTD

Contact:86-511-85210668 0511-85210668, 85210818, 85210898

Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Zhengzhou Institute of Chiral Pharmer Research Co., Ltd.

Contact:86-371-55219111

Address:15 Floor, 2 Building, Central China Technovalley, Zhongyuan West Road
Hangzhou Gangjin Chemical Co.,Ltd.(expird)

Contact:+86-571-85109780

Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China

Relevant to this article

One Step Backward Is Two Steps Forward: Enhancing the Hydrolysis Rate of UiO-66 by Decreasing [OH^-]

Doi:10.1021/acscatal.5b00785
(2015)
Highly Efficient Selective Monohydrolysis of Symmetric Diesters

Doi:10.1021/jo0001986
(2000)
A furazan-fused pyrazole N-oxide via unusual cyclization

Doi:10.1039/c7ta00846e
(2017)
Titanium and ruthenium binaphthyl Schiff base complexes as catalysts for asymmetric trimethylsilylcyanation of aldehydes

Doi:10.1039/a904330f
(1999)
Doi:10.1016/S0020-1693(00)90487-0
(1981)
Doi:10.1246/bcsj.52.1944
(1979)

Article Doi