Journal of Fluorine Chemistry p. 231 - 236 (1994)
Update date:2022-08-11
Topics:
Pustovit, Yu. M.
Ogojko, P. I.
Nazaretian, V. P.
Rozhenko, A. B.
Treatment of gem-dichlorocyclopropanecarboxylic acids with SF4 yields many rearranged products, i.e. 1,1-difluoro-substituted olefins.The mechanism of the rearrangement is discussed. - Keywords: Cycloalkanecarboxylic acids; Sulphur tetrafluoride; Rearrangement mechanism; Stereochemistry; NMR spectroscopy; IR spectroscopy
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