Reactions of cycloalkanecarboxylic acids with SF4. II. Fluorination of gem-dichlorocyclopropanecarboxylic acids with SF4

DOI: 10.1016/0022-1139(93)02995-Q

Source and publish data:

Journal of Fluorine Chemistry p. 231 - 236 (1994)

Update date:2022-08-11

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Authors:

Pustovit, Yu. M.

Ogojko, P. I.

Nazaretian, V. P.

Rozhenko, A. B.

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Article abstract of DOI:10.1016/0022-1139(93)02995-Q

Treatment of gem-dichlorocyclopropanecarboxylic acids with SF4 yields many rearranged products, i.e. 1,1-difluoro-substituted olefins.The mechanism of the rearrangement is discussed. - Keywords: Cycloalkanecarboxylic acids; Sulphur tetrafluoride; Rearrangement mechanism; Stereochemistry; NMR spectroscopy; IR spectroscopy

Full text of DOI:10.1016/0022-1139(93)02995-Q

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