Tetrahedron Letters p. 2773 - 2776 (1982)
Update date:2022-08-11
Topics:
Blonski, C.
Gasc, M. B.
Klaebe, A.
Perie, J. J.
This work describes the reversible C-addition of a sterically hindered-P thiophosphoric ester to a carbodiimide, as a model of activated biotin.The formed intermediate, is found to be in equilibrium with the corresponding N-phosphorylated thiourea.The entire system is controlled by proton transfer and reversible.
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