Tetrahedron Letters p. 3305 - 3308 (1994)
Update date:2022-08-11
Topics:
Vanelle, Patrice
Donini, Santa
Maldonado, Jose
Sabuco, Jean-Francois
Crozet, Michel P.
The C-alkylation reaction of 2-chloromethyl-4,9-dihydro-1-methyl-1H-naphtho[2,3-d]imidazol-4,9-dion e by 2-nitropropane anion is shown to proceed by the S(RN)1 mechanism. This mechanism is confirmed by the inhibitory effects of dioxygen, p-dinitrobenzene, cupric chloride and TEMPO.
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