Journal of Physical Chemistry p. 17 - 21 (1980)
Update date:2022-08-16
Topics:
Napoleone, V.
Schelly, Z. A.
The kinetics and mechanism of the reaction between NOCl and n-BuOH is investigated at 5 and 22 deg C in CCl4-HOAc mixtures, ranging from pure CCl4 to 75percent v/v HOAc.In the solvent mixtures, the use of the solvent-jump relaxation method is demonstrated on this reaction which is insensitive to concentration-jump but is perturbable by a sudden change of the reaction medium.The experimental relaxation amplitudes are in agreement with the ones calculated theoretically, and the ratios of the rate constants k1/k-1 agree with the equilibrium constants K determined photometrically.The variation of the thermodynamic and activation parameters is discussed as a function of solvent composition.
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