Journal of Physical Chemistry p. 17 - 21 (1980)
Update date:2022-08-16
Topics:
Napoleone, V.
Schelly, Z. A.
The kinetics and mechanism of the reaction between NOCl and n-BuOH is investigated at 5 and 22 deg C in CCl4-HOAc mixtures, ranging from pure CCl4 to 75percent v/v HOAc.In the solvent mixtures, the use of the solvent-jump relaxation method is demonstrated on this reaction which is insensitive to concentration-jump but is perturbable by a sudden change of the reaction medium.The experimental relaxation amplitudes are in agreement with the ones calculated theoretically, and the ratios of the rate constants k1/k-1 agree with the equilibrium constants K determined photometrically.The variation of the thermodynamic and activation parameters is discussed as a function of solvent composition.
View More
Contact:86-10-62664360
Address:Building 10,No.18 AnNingZhuang East Road, GuangHua Pioneer Park,HaiDian District, BeiJing China
Jinhua City Mingzhu Pharmaceutical Co.,Ltd.
Contact:15857995878 0579-82207761
Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua
Shanghai Mio Chemical Co., Ltd
Contact:0086 21- 64401188-622
Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Suzhou Wedo Chemicals Co., Ltd.
Contact:86 512 58100425
Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
Hangzhou Neway Chemicals Co., Ltd.
Contact:+86-571-85095566
Address:Room 803, Qinglian Bldg, No 139 Qingchun Road, Hangzhou, Zhejiang China
Doi:10.1021/jo01036a013
(1963)Doi:10.1016/S0031-9422(00)97564-2
(1992)Doi:10.1016/j.ejmech.2019.06.016
(2019)Doi:10.1016/S0040-4039(00)71375-X
(1980)Doi:10.1016/j.tet.2014.10.066
(2014)Doi:10.1016/S0040-4039(00)92999-X
(1976)
