Steroids p. 786 - 790 (1995)
Update date:2022-08-17
Topics:
Skoda-Foeldes, Rita
Csakai, Zita
Kollar, Laszlo
Szalontai, Gabor
Horvath, Judit
Tuba, Zoltan
17-Iodo-Δ16 steroids undergo selective dimerization and carbonylative dimerization in the presence of palladium catalysts in dimethylformamide which result in 16-17'-coupled dienes and 17-carboxylic anhydrides, respectively.Moderate to good yields have been obtained for both types of dimers. - Keywords: dehalodimerization of steroids; steroidal anhydrides; conjugated dimeric dienes; homogeneous palladium(0) catalysts
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Doi:10.1021/ja01158a062
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(2017)
