Homogeneous catalytic dehalodimerization of 17-iodo-Δ16 steroids

DOI: 10.1016/0039-128X(95)00120-F

Source and publish data:

Steroids p. 786 - 790 (1995)

Update date:2022-08-17

Topics:

Authors:

Skoda-Foeldes, Rita

Csakai, Zita

Kollar, Laszlo

Szalontai, Gabor

Horvath, Judit

Tuba, Zoltan

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Article abstract of DOI:10.1016/0039-128X(95)00120-F

17-Iodo-Δ¹⁶ steroids undergo selective dimerization and carbonylative dimerization in the presence of palladium catalysts in dimethylformamide which result in 16-17'-coupled dienes and 17-carboxylic anhydrides, respectively.Moderate to good yields have been obtained for both types of dimers. - Keywords: dehalodimerization of steroids; steroidal anhydrides; conjugated dimeric dienes; homogeneous palladium(0) catalysts

Full text of DOI:10.1016/0039-128X(95)00120-F

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