HIGHLY STEREOSELECTIVE CLAISEN REARRANGEMENT OF VINYL ETHER OF 1-(1-HYDROXYETHYL)-2-METHYL-3-ALKYLCYCLOPENTENE. A ROUTE TO CIS- AND TRANS(1E)-ETHYLIDENE-8-METHYLHYDRINDAN-5-ONE.

DOI: 10.1016/S0040-4039(00)86793-3

Source and publish data:

Tetrahedron Letters p. 233 - 234 (1982)

Update date:2022-08-17

Topics:

Authors:

Takahashi, Takashi

Yamada, Haruo

Tsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4039(00)86793-3

The highly stereoselective Claisen rearrangement of the α-isomer of vinyl ether of 1-(1-hydroxyethyl)-2-methyl-3-alkylcyclopentene introduces the trans stereochemistry between C(8)methyl and C(9)hydrogen and the geometry of E-olefin, necessary for a synth

Full text of DOI:10.1016/S0040-4039(00)86793-3

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