
Helvetica Chimica Acta p. 57 - 62 (1980)
Update date:2022-08-11
Topics:
Grob, Cyril A.
Schaub, Bruno
Schlageter, Markus G.
pKa Values of 42 quinuclidinium perchlorates I have been measured in 0.1M aqueous KCl-solution.In a few cases small corrections of earlier thermodynamic pKa values are indicated.These measurements, in conjuction with recent X-ray structure determinations, confirm the reliability of the inductive substituent constants ?qI derived from them.
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