Zinc chlorochromate nonahydrate [Zn(ClCrO3)2.9H2O] is a useful reagent for the solvent-free and in solution oxidative deprotection of trimethyl- and tert-butyldimethylsilyl ethers

Article abstract of DOI:10.1080/10426509908044972

Primary and secondary tert-butyldimethylsilyl and trimethylsilyl ethers are oxidized to their corresponding carbonyl compounds with zinc chlorochromate nonahydrate (ZCCNH) in dichloromethane or under solvent free conditions in good yields. For comparison, we have also studied the reactions with pyridinium chlorochromate (PCC) under similar reaction conditions.

Full text of DOI:10.1080/10426509908044972

This article was downloaded by: [McMaster University]
On: 25 December 2014, At: 21:20
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Phosphorus, Sulfur, and Silicon
and the Related Elements
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/gpss20
ZINC CHLOROCHROMATE
NONAHYDRATE
[Zn(ClCrO3)2.9H2O] IS A
USEFUL REAGENT SOLUTION
OXIDATIVE DEPROTECTION
FOR THE SOLVENT-FREE AND
IN OF TRIMETHYL- AND TERT-
BUTYLDIMETHYLSILYL ETHERS
Habib Firouzabadi a , Mostafa Gholizadeh a &
Mahmood Fakourpour a
a Department of Chemistry , Shiraz University ,
Shiraz, 71454, Iran
Published online: 04 Oct 2006.
To cite this article: Habib Firouzabadi , Mostafa Gholizadeh & Mahmood Fakourpour
(1999) ZINC CHLOROCHROMATE NONAHYDRATE [Zn(ClCrO3)2.9H2O] IS A USEFUL
REAGENT SOLUTION OXIDATIVE DEPROTECTION FOR THE SOLVENT-FREE AND IN OF
TRIMETHYL- AND TERT-BUTYLDIMETHYLSILYL ETHERS, Phosphorus, Sulfur, and Silicon
and the Related Elements, 155:1, 81-87, DOI: 10.1080/10426509908044972
To link to this article: http://dx.doi.org/10.1080/10426509908044972
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no

representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions