α-Tolylsulfinylation of ketones via their trimethylsilyl enol ethers. One-step synthesis of β-ketosulfoxides

Article abstract of DOI:10.1080/00397919308011245

Ketones are reported to be conveniently converted into their α-tolylsulfinylated derivatives. This new procedure is based on the reaction of their corresponding trimethylsilyl enol ethers with p-toluenesulfinyl p-tolylsulfone in the presence of tris(dimet

Full text of DOI:10.1080/00397919308011245

This article was downloaded by: [130.132.123.28]
On: 23 December 2014, At: 21:33
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
α-Tolylsulfinylation of Ketones
via Their Trimethylsilyl Enol
Ethers. One-Step Synthesis of
β-Ketosulfoxides
Romualdo Caputo a , Carla Ferreri a , Luigi
Longobardo a , Giovanni Palumbo a & Silvana
Pedatella a
a Dipartimento di Chimica Organica e Biologica ,
Università degli Studi di Napoli Federico II Via
Mezzocannone , 16 I-80134, Napoli, Italy
Published online: 23 Sep 2006.
To cite this article: Romualdo Caputo , Carla Ferreri , Luigi Longobardo , Giovanni
Palumbo & Silvana Pedatella (1993) α-Tolylsulfinylation of Ketones via Their
Trimethylsilyl Enol Ethers. One-Step Synthesis of β-Ketosulfoxides, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 23:11, 1515-1522, DOI: 10.1080/00397919308011245
To link to this article: http://dx.doi.org/10.1080/00397919308011245
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,

or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions