Tetrahedron p. 2881 - 2885 (1981)
Update date:2022-08-17
Topics:
Moehrle, H.
Troester, G.
Linden, M.
Mootz, D.
Wunderlich, H.
Mercury EDTA dehydrogenation of 2-(pyrrolidinomethyl)-pyridine-1-oxide (1) yields the pyrrolidone 5, which may be accounted for by a neighbouring effect of the amine oxide group.For an additional basic product the structure of (E)-2-(1-pyrroline-3-ylidenemethyl)-pyridine-1-oxide (11) has been proved by X-ray crystallography and synthesis.This indicates a cleavage of the doubly dehydrogenated product followed by recombination.
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(1968)Doi:10.1081/SCC-100107021
(2001)Doi:10.1016/S0040-4039(98)02017-6
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(1995)
