Diastereoselective route to the tetrahydropyranoid core of the polyketide herbicide herboxidiene

DOI: 10.1039/cc9960000723

Source and publish data:

Chemical Communications p. 723 - 724 (1996)

Update date:2022-08-22

Topics:

Authors:

Banwell, Martin G.

Bui, Chinh T.

Simpson, Gregory W.

Watson, Keith G.

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Article abstract of DOI:10.1039/cc9960000723

Nerol 15 is readily converted, via initial asymmetric epoxidation, into compound 2 which contains the tetrahydropyranoid core of herboxidiene 1, a potent phytotoxic compound isolated from Streptomyces sp. A7847.

Full text of DOI:10.1039/cc9960000723

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