Gif-type oxidation systems. Evidence for a second intermediate between saturated hydrocarbon and ketone

DOI: 10.1016/0040-4039(90)80156-G

Source and publish data:

Tetrahedron Letters p. 2717 - 2820 (1990)

Update date:2022-08-30

Topics:

Authors:

Barton Barton

Csuhai Csuhai

Ozbalik Ozbalik

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Article abstract of DOI:10.1016/0040-4039(90)80156-G

The addition of dianisyl telluride to a Gif(IV) oxidation of adamantane has a marked effect on the ratio of ketone to secondary alcohol formed. This is interpreted as an indication of a second intermediate in the conversion of saturated hydrocarbvons into ketones. This second intermediate is probably an Fe(III) alkoxide.

Full text of DOI:10.1016/0040-4039(90)80156-G

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