
Tetrahedron Letters p. 2717 - 2820 (1990)
Update date:2022-08-30
Topics:
Barton
Csuhai
Ozbalik
The addition of dianisyl telluride to a Gif(IV) oxidation of adamantane has a marked effect on the ratio of ketone to secondary alcohol formed. This is interpreted as an indication of a second intermediate in the conversion of saturated hydrocarbvons into ketones. This second intermediate is probably an Fe(III) alkoxide.
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