Asymmetric Hydrogenation Cazalyzed by Bis(disubstitiuted glyoximato)cobalt(II)-Chiral Cocatalyst System. Effect of Structural Variation of Ligands and Hydrogen Pressure

DOI: 10.1246/bcsj.60.1549

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Bulletin of the Chemical Society of Japan p. 1549 - 1551 (1987)

Update date:2022-08-11

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Authors:

Ohgo, Yoshiaki

Tashiro, Yasuhisa

Takeuchi, Seiji

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Article abstract of DOI:10.1246/bcsj.60.1549

The reaction rate was extremely enhanced by increasing the basicity of the axial ligand of and by increasing the hydrogen pressure without decreasing the enantioselectivity.Substituting one and two methyl groups of the dimethylglyoxime liga

Full text of DOI:10.1246/bcsj.60.1549

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