η-Cyclopentadienyltungsten Compounds with Vinyl- and Allyl-phosphine Ligands

DOI: 10.1039/DT9940000871

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 871 - 878 (1994)

Update date:2022-08-11

Topics:

Authors:

Morise, Xavier

Green, Malcolm L. H.

McGowan, Patrick C.

Simpson, Stephen J.

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Article abstract of DOI:10.1039/DT9940000871

The properties as ligands of the primary phosphines PH2(CH=CH2) 1 PH2(CH2CH=CH2) 2 have been studied.The new compounds (R 5= H4-i-Pr, R'= CH=CH2 7 or CH2CH=CH2 8; R5 = Me4Et, R' = CH=CH2 9 or CH2CH=CH2 10), (X = Cl, R = CH=CH2 12 or CH2CH=CH2 13; X = Br, R = CH=CH2 15), 17 and 18 have been prepared.The crystal structures of compounds 10 and 17 have been determined.

Full text of DOI:10.1039/DT9940000871

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