A synthesis of allylboronates via the palladium(0)-catalyzed cross-coupling reaction of bis(pinacolato)diboron with allylic acetates

DOI: 10.1016/0040-4039(96)01505-5

Source and publish data:

Tetrahedron Letters p. 6889 - 6892 (1996)

Update date:2022-08-11

Topics:

Authors:

Ishiyama, Tatsuo

Ahiko, Taka-Aki

Miyaura, Norio

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Article abstract of DOI:10.1016/0040-4039(96)01505-5

The cross-coupling reaction of bis(pinacolato)diboron [(Me₄C₂O₂)BB(O₂C₂Me₄)] with allyl acetates regio- and E-stereoselectively provided the pinacol esters of allylboronic acids in high yields. The reaction was efficiently catalyzed by Pd[dba]₂ in DMSO at 50°C.

Full text of DOI:10.1016/0040-4039(96)01505-5

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