Chemical conversion of humulene to dactylol. Biomimetic, apparent 1,2-shift of a methyl group

DOI: 10.1016/S0040-4039(00)61952-4

Source and publish data:

Tetrahedron Letters p. 873 - 876 (1985)

Update date:2022-08-11

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Authors:

Hayasaka, Kazuhiro

Ohtsuka, Toshikazu

Shirahama, Haruhisa

Matsumoto, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(00)61952-4

Africanol, which had been previously derived from humulene, was converted to dactylol through a formal 1,2-shift of a methyl group, which involved a cyclopropane sliding reaction and subsequent cyclopropane ring opening.

Full text of DOI:10.1016/S0040-4039(00)61952-4

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