Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 609 - 616 (1988)
Update date:2022-08-17
Topics:
Chandra, Harish
Keeble, David J.
Symons, Martyn C. R.
Exposure of dilute solutions containing nitrosobenzene in trichlorofluoromethane to 60Co γ-rays at 77 K gave the corresponding radical cation, characterised by e.s.r. spectroscopy.The results confirm the interpretation of liquid-phase data assigned to this cation, which showed that loss is from an in-plane ?-orbital localised on nitrogen and oxygen, rather than from the aromatic ?-system.However, solutions containing the t-butyl derivative in equilibrium with its dimer, (Me3CNO)2, gave primarily the dimer cation, (Me3CNO)2+, with possible traces of the monomer cation.The e.s.r. data for the latter resemble those for the nitrosobenzene cation, whereas results for the dimer cation suggest that loss is from a ?-type orbital with very low spin density on the two equivalent nitrogen atoms.
View MoreShaanxi Sinuote Biotech Co.,Ltd
Contact:+86-29-68859685
Address:No 18,Taiyuan Road ,Xi'an city ,China
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.
Contact:+86-(574)-81110986
Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Twin International Co., Limited
Contact:+86-21-80309280
Address:No.345 Jinxiang Road, Jinqiao Export Processing Zone
Contact:+86-27-85733560
Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
website:http://www.chemdow.com
Contact:0086-10-82435335
Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
Doi:10.1016/0009-2614(91)90416-7
(1991)Doi:10.1039/c39820000176
(1982)Doi:10.1021/jo00063a050
(1993)Doi:10.1246/bcsj.62.3518
(1989)Doi:10.1002/hlca.19700530821
(1970)Doi:10.1002/aoc.3776
(2017)
