Tetrahedron Letters p. 7235 - 7238 (1993)
Update date:2022-08-17
Topics:
Ashby
Welder, Catherine O.
Doctorovich, Fabio
Reactions of the noncyclizable alkyl iodide, 1-iodo-2,2-dimethylhexane (9), with LiAlH4 and LiAlD4 have been carried out under a variety of conditions. Although the structure of 9 prohibits a halogen atom radical chain process, deuterium incorporation studies provide convincing evidence for single electron transfer (SET) as the major reaction pathway.
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