FORMATION OF 10b,10c-DIHYDRO-10b,10c-DIMETHYLPYRENES IN REACTION OF 8,16-DIMETHYLMETACYCLOPHAN-1-ENES WITH PROTONIC ACIDS

DOI: 10.1246/cl.1985.327

Source and publish data:

Chemistry Letters p. 327 - 328 (1985)

Update date:2022-08-11

Topics:

Authors:

Tashiro, Masashi

Kobayashi, Kazumasa

Yamato, Takehiko

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Article abstract of DOI:10.1246/cl.1985.327

Reaction of 8,16-dimethyl<2.2>metacyclophan-1-enes with protonic acids such as 57percent hydroiodic acid and trifluoroacetic acid afforded the corresponding 10b,10c-dihydro-10b,10c-dimethylpyrenes.Similar reaction with 47percent hydrobromic acid and 36percent hydrochloric acid gave surprisingly halogenated 10b,10c-dihydro-10b,10c-dimethylpyrenes.

Full text of DOI:10.1246/cl.1985.327

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