Organic Mass Spectrometry p. 451 - 457 (1987)
Update date:2022-08-03
Topics:
Bouchoux, Guy
Tortajada, Jeanine
Dagaut, Jacques
Fillaux, Joelle
The metastable molecular ion of 2-hexanone loses a methyl radical mainly (ca. 80percent) from positions C(4) and C(6), in equal proportions, as indicated by 13C labelling.The necessary skeletal rearrangement of the butyl chain is interpreted in terms of a 1,2-
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