Studies toward the diastereoselective reduction of 2-alkoxycarbonyl-2-allyl-cyclopentanone derivatives with boron hydrides

Article abstract of DOI:10.1080/00397919508012677

The reduction of 2-alkoxycarbonyl-2-allyl-cyclopentanone derivatives with inexpensive boron hydrides were studied showing that this process depend on chelation factors instead steric ones, affording the isomeric alcohols 2a and 3a with high diastereomeric

Full text of DOI:10.1080/00397919508012677

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Synthetic Communications: An
International Journal for Rapid
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Organic Chemistry
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Studies Toward the
Diastereoselective Reduction
of 2-Alkoxycarbonyl-2-allyl-
cyclopentanone Derivatives
with Boron Hydrides
Carlos A. M. Fraga a & Eliezer J. Barreiro a
a Laboratório de AvaliacęLião de Síntese de
Substacirc;ncias Bioativas (L.A.S.S. Bio), Faculdade
de Farmácia, Universidade Federal do Rio de
Janeiro, C.P. 68006, ZIP-21944190, Rio de Janeiro,
R.J., Brazil
Version of record first published: 23 Sep 2006.
To cite this article: Carlos A. M. Fraga & Eliezer J. Barreiro (1995): Studies Toward
the Diastereoselective Reduction of 2-Alkoxycarbonyl-2-allyl-cyclopentanone
Derivatives with Boron Hydrides, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 25:8, 1133-1144
To link to this article: http://dx.doi.org/10.1080/00397919508012677
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