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ChemComm
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COMMUNICATION
Journal Name
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Fig. 4. TEM images of An-MnMo6 covalent polymer in (A) fibrous
bundles, (B) isolated single chain and (C) local amplification.
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(Fig. S24, ESI†). In the case of further irradiation for 5 h, the Mw
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coupling reaction without the presence of γ-CD leads to the
more flexible polymers and the exposed organic moiety with
hydrophobicity makes the polymer less water-soluble, resulting
in irregular globular aggregates.
In summary, we demonstrate a supramolecular strategy to 20 A. Macdonell, N. A. Johnson, A. J. Surman and L. Cronin, J.
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polymerize an Anderson-Evans POM cluster via a host-guest
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of supramolecular and covalent polymers, but also build a shish
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inorganic cluster and cyclodextrin are threaded together
alternately. Owing to the chain rigidity, we firstly observed the
morphology of the single-strand and the induced chirality in the
hybrid polymer is confirmed. It is sure that such
a
supramolecular method is extendable for controlled 26 T. Tamaki, T. Kokubu and K. Ichimura, Tetrahedron, 1987, 43,
1485–1494.
polymerization of POM-contained functional materials and
development of two-dimensional structures via crosslinking.
The authors acknowledge the financial supports from NSFC
(21574057, 21773090), Changbaishan Distinguished Professor
27 C. Yang, T. Mori, Y. Origane, Y. H. Ko, N. Selvapalam, K. Kim
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28 J. W. Chung, T. J. Kang and S.-Y. Kwak, Macromolecules,
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Funding of Jilin Province, and the Program for JLU Science and 29 J. Szejtli, Chem. Rev., 1998, 98, 1743–1754.
30 M. Otagiri, K. Ikeda, K. Uekama, O. Ito and M. Hatano, Chem.
Technology Innovative Research Team (2017TD-10). We thank
Mr. Hao Zhang for his help in SLS experiment.
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31 Pierre R. Marcoux, B. Hasenknopf, J. Vaissermann and P.
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32 R. More, M. Scholz, G. Busse, L. Busse, C. Paulmann, M.
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Conflicts of interest
There are no conflicts to declare.
33 L. Zhu, A. Agarwal, J. Lai, R. O. Al-Kaysi, F. S. Tham, T.
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4 | J. Name., 2012, 00, 1-3
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