Tetrahedron Letters p. 2755 - 2758 (1985)
Update date:2022-08-16
Topics:
Majetich, Georg
Hull, Ken
Defauw, Jean
Shawe, Thomas
The geometrical constraints of the fluoride-initiated and Lewis acid-catalyzed intramolecular addition of allylsilanes to enone systems were shown to be governed by kinetic-ring-size preferences.Molecules containing adjacent quaternary carbon atoms can be prepared using this method.
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