GEOMETRICAL LIMITATIONS IN THE INTRAMOLECULAR ADDITION OF UNSYMMETRICAL ALLYLSILANES TO ENONES

DOI: 10.1016/S0040-4039(00)94903-7

Source and publish data:

Tetrahedron Letters p. 2755 - 2758 (1985)

Update date:2022-08-16

Topics:

Authors:

Majetich, Georg

Hull, Ken

Defauw, Jean

Shawe, Thomas

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Article abstract of DOI:10.1016/S0040-4039(00)94903-7

The geometrical constraints of the fluoride-initiated and Lewis acid-catalyzed intramolecular addition of allylsilanes to enone systems were shown to be governed by kinetic-ring-size preferences.Molecules containing adjacent quaternary carbon atoms can be prepared using this method.

Full text of DOI:10.1016/S0040-4039(00)94903-7

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