Synthesis of the sesquiterpenoid trichodiene using a free radical fragmentation approach

DOI: 10.1016/S0040-4039(98)01140-X

Source and publish data:

Tetrahedron Letters p. 5489 - 5492 (1998)

Update date:2022-08-16

Topics:

Authors:

Lange, Gordon L.

Furlan, Lorena

MacKinnon, Mark C.

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Article abstract of DOI:10.1016/S0040-4039(98)01140-X

A highly regio- and stereoselective synthesis of the sesquiterpenoid trichodiene is reported. The approach requires only nine steps starting with a [2+2] photoaddition and employs the free radical fragmentation of an 'external' cyclobutane bond in a key step.

Full text of DOI:10.1016/S0040-4039(98)01140-X

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