Journal of the Chemical Society. Chemical communications p. 305 - 306 (1987)
Update date:2022-08-16
Topics:
Basha, Anwer
Brooks, Dee W.
Lithium carbanions add sequentially to O-benzyl-N-methylenehydroxylamine (1), first at the electrophilic carbon and subsequently, at higher temperature, on the nitrogen with concomitant loss of the benzyloxy group, resulting in a CH2+-NH+ synthetic equivalent, the amines (4) being produced.
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