First examples of cobalt-mediated formal Alder ene reaction of allenynes

DOI: 10.1016/0040-4039(96)01538-9

Source and publish data:

Tetrahedron Letters p. 7027 - 7030 (1996)

Update date:2022-08-18

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Authors:

Llerena, Dominique

Aubert, Corinne

Malacria, Max

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Article abstract of DOI:10.1016/0040-4039(96)01538-9

CpCo(CO)₂ catalyzes the Alder ene reaction of allenynes 1 to afford six-membered carbocycles in a totally regioselective manner through, presumably, η³-allyl hydride complexes mechanism.

Full text of DOI:10.1016/0040-4039(96)01538-9

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