Tetrahedron p. 6739 - 6748 (1999)
Update date:2022-08-28
Topics:
Arrowood, Tina L.
Kass, Steven R.
The synthesis of 3-substituted-3-(trimethylsilyl)cyclopropenes (X = CO2Et, CHO, CN) is described. Their acid sensitivity and thermal stability was probed and the reaction products were identified. In one case, a novel rearrangement to a Dewar furan maybe involved and this pathway was explored via kinetics and computations.
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