Journal of Organometallic Chemistry p. 169 - 178 (1982)
Update date:2022-08-17
Topics:
Isnard, P.
Denise, B.
Sneeden, R.P.A.
Cognion, J.M.
Durual, P.
A study has been made of the catalytic activities of various ruthenium complexes in the synthesis of ketones from olefin-carbon monoxide mixtures and an alcohol as source of hydrogen: major side products were shown to be the alkyl propionates and ethane.The effects of base, concentration of catalyst (for RuCl3- and Ru3(CO)12-based systems), pressure, temperature, CO/olefin ratio and the water content of the alcohol have been examined.
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