Journal of the Chemical Society. Perkin transactions II p. 1437 - 1440 (1980)
Update date:2022-08-17
Topics:
Said, Zainuddin
Tillett, John G.
The acid catalysed hydrolysis of ethyloxatriazole has been studied in aqueous solutions of mineral acids at 120°C. Analyses of the data by Bunnett and Bunnett-Olsen criteria and entropies of activation are consistent with a gradual change-over from an A-2 mechanism at low acid concentration to a predominantly A-1 mechanism at high acidities. Values of the kinetic solvent isotope effect indicate the involvement of a modified A-2 mechanism in which a proton transfer is partially rate determining.
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(1963)
