Journal of Organometallic Chemistry p. 15 - 24 (1980)
Update date:2022-08-17
Topics:
Larson, Gerald L.
Argueelles, Rafael
Rosario, Osvaldo
Sandoval, Sydia
The generation of α-silyl-α-borylmethane derivatives as intermediates and their oxidation to α-hydroxyorganosilanes is reported.The formation of the intermediate α-silyl-α-borylmethane derivatives is via the type I transfer reaction of organoboranes with either (trimethylsilyl)bromomethyllithium and (phenyldimethylsilyl)chloromethyllithium in THF or in some cases hexane.
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