Chemistry of Materials p. 6257 - 6264 (2014)
Update date:2022-08-17
Topics:
Bromberg, Lev
Su, Xiao
Hatton, T. Alan
The creation of functional porous nanoscale networks with enhanced reactive group accessibility provides rich promise for novel designs of composite materials. We present a straightforward strategy for the preparation of porous polymer/MOF hybrids via polymerization of organic monomers and cross-linkers impregnated within the pores of the MOFs followed by functionalization of the resulting composite. A poly(maleimide-co-dibinylbenzene) network was synthesized in the presence of MOF MIL-101(Cr), resulting in stable hybrid composites, which were then brominated to give porous hybrids of cross-linked poly(N-bromomaleimide), a polymeric analogue of N-bromosuccinimide, interconnected with crystalline nanoparticles of the MOF. Due to the large porosity and surface area, the active bromine (halamine) groups in the polymer network enabled high activity of the composites in heterogeneous catalysis of conversion of d-fructose into 5-hydroxymethylfurfural.
View MoreHangzhou Taiyan Trading Co., Ltd
Contact:+86-13777583958
Address:NO.63, Xingyi Street, Xihu District, Hangzhou, Zhejiang, China
Xiamen Goodhealth Pharmchem Co., Ltd.
Contact:0086-592-2097683
Address:404R No.2 54# Minzu Rd., Xiamen, China
Jiangsu Glory Chemical Co., Ltd.
Contact:+86-571-87896791
Address:Yanhua Chemical Park, Hongze, Huai'an, Jiangsu, China
HANGZHOU FOREWIN PHARMA CO., LTD
Contact:+86-571-89053961
Address:hangzhou
Suzhou Lixin Pharmaceutical Co., Ltd.
Contact:86-512-88169812
Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
Doi:10.1021/j100325a004
(1988)Doi:10.1016/S0040-4039(97)01720-6
(1997)Doi:10.1080/00397910903097336
(2010)Doi:10.1021/bi00773a021
(1972)Doi:10.1021/acs.jnatprod.0c01186
(2021)Doi:10.3390/molecules16108614
(2011)