Journal of the Chemical Society. Chemical communications p. 164 - 165 (1984)
Update date:2022-08-10
Topics:
Hendry, Philip
Sargeson, Alan M.
The base hydrolysis of trimethyl phosphate to yield dimethyl phosphate and methanol is accelerated 400-fold upon co-ordination to the penta-ammineiridium(III) moiety; the reaction proceeds via intermolecular attack of hydroxide ion at the phosphorus centre in both co-ordinated and free ligand.
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