Journal of Fluorine Chemistry p. 169 - 174 (1994)
Update date:2022-08-17
Topics:
Seifert, Frank U.
Roeschenthaler, Gerd-Volker
1,1,1,3,3-Pentafluoropropane-2-one (3) (pentafluoroacetone) is readily obtained from 1,1,1,3,3,3-hexafluoropropane-2-ol by dehydrofluorination using lithium bis(trimethylsilyl)amide, followed by isomerization of 1,1,3,3,3-pentafluoropropene-2-ol.Pentafluoroacetone adds trimethylsilylphosphites to yield α-trimethylsiloxyphosphonates which, upon thermolysis, furnish (Z)-1,3,3,3-tetrafluoropropenyldialkylphosphites and (Z)-1,3,3,3-tetrafluoro-2-trimethylsiloxypropene.
View More
Contact:86-571-61063068
Address:LINAN
Contact:+86-515-88356562
Address:No.2, West Daqing Road, Yancheng, Jiangsu, China
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd
Contact:+86-533-5415882
Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Contact:86-931-8272767
Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
Shenyang NovPharm Technology Co., Ltd.
Contact:.+86-24-24165786
Address:Room 306, Hongjin Mansion, No. 36-1, Wanliutang Rd., Shenhe District, Shenyang, Liaoning, P.R.C.
Doi:10.1109/40.865865
(1894)Doi:10.1021/ja01215a021
(1946)Doi:10.1016/j.poly.2015.09.071
(2015)Doi:10.1016/j.catcom.2020.106275
(2021)Doi:10.1016/j.tet.2015.12.062
(2016)Doi:10.1021/jf000493r
(2001)
