Dramatic Acceleration of Migratory Insertion in - by Methanol and by Tin(II) Iodide

DOI: 10.1039/c39950001045

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1045 - 1046 (1995)

Update date:2022-08-11

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Authors:

Pearson, Jean M.

Haynes, Anthony

Morris, George E.

Sunley, Glenn J.

Maitlis, Peter M.

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Article abstract of DOI:10.1039/c39950001045

Carbonylation of - to - requires temperatures >80 deg C in chlorobenzene, but is dramatically accelerated on addition of methanol (x10⁴ at 33 deg C) or of the Lewis acid SnI2 (x200 at 93 deg C); the acceleration is p

Full text of DOI:10.1039/c39950001045

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