New Synthetic Routes to β-Olefinic Trialkoxyphosphonium Salts and Phosphonates: Organometallic Variants of the Michaelis-Arbuzov Reaction

DOI: 10.1002/hlca.19860690733

Source and publish data:

Helvetica Chimica Acta p. 1757 - 1767 (1986)

Update date:2022-08-11

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Authors:

Hafner, Andreas

Philipsborn, Wolfgang von

Salzer, Albrecht

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Article abstract of DOI:10.1002/hlca.19860690733

The low-temperature addition of tertiary phosphites to <(allyl)Fe(CO)4>⁺X^- complexes proceeds regio- and stereospecifically and produces metal-coordinated β-olefinic trialkoxyphosphonium ions.These can be converted by various routes

Full text of DOI:10.1002/hlca.19860690733

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