
Chemistry Letters p. 1385 - 1388 (1993)
Update date:2022-08-30
Topics:
Kobayashi, Shiro
Cao, Shaokui
Higher molecular wight polygermanes were synthesized by a ligand substitution polymerization of the 1,4-dioxane complex of germanium dichloride with organolithium compounds at a lower reaction temperature.Different from conventional Wurtz-type coupling reaction, the present polymerization gives rise much higher yields of polygermanes.
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