Diisopropyl tartrate-modified (E)-γ-[(menthofuryl)dimethylsilyl]-allyl boronate, an improved chiral reagent for the anti α-hydroxyallylation of aldehydes. Application to the enantioselective synthesis of (-)-swainsonine

DOI: 10.1016/0040-4039(94)02295-M

Source and publish data:

Tetrahedron Letters p. 501 - 504 (1995)

Update date:2022-08-17

Topics:

Authors:

Hunt Hunt

Roush Roush

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Article abstract of DOI:10.1016/0040-4039(94)02295-M

An enantioselective synthesis of anti 1,2-diols via the reactions of aldehydes and the tartrate ester-modified (E)-γ-(menthofurylsilyl)allylboronate 5 has been developed. This methodology is applied to a brief, enantioselective synthesis of (-)-swainsonine.

Full text of DOI:10.1016/0040-4039(94)02295-M

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