Synthesis of sulfines by oxidation of trithioperesters and their rearrangement into acyltrisulfides

DOI: 10.1016/S0040-4039(00)77070-5

Source and publish data:

Tetrahedron Letters p. 5229 - 5230 (1994)

Update date:2022-09-26

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Authors:

Leriverend, Catherine

Metzner, Patrick

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Article abstract of DOI:10.1016/S0040-4039(00)77070-5

Trithioperesters were synthesised by sulfenylation of halomagnesium alkanedithioates with alkylthiotoluenesulfonates and oxidised by mCPBA.The chemoselective conversion of a thiocarbonyl group into a sulfine moiety was achieved in three cases to yield the

Full text of DOI:10.1016/S0040-4039(00)77070-5

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