Asymmetric Reduction of Acylstannanes. Preparation of Enantiomerically Enriched α-Alkoxystannanes

DOI: 10.1021/jo00258a048

Source and publish data:

Journal of Organic Chemistry p. 5584 - 5586 (1988)

Update date:2022-08-16

Topics:

Authors:

Chan, Philip C.-M.

Chong, J. Michael

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00258a048

Reduction of acylstannanes (5) with BINAL-H reagents affords α-hydroxystannanes in reasonable chemical (45-69percent) and consistently good optical (up to 96percent ee) yields with predictable stereochemistry.

Full text of DOI:10.1021/jo00258a048

Products guided by the article

Product name:((R)-sec-Butoxymethoxymethyl)-benzene

Cas No:73255-17-1

R&D Labs maybe for 73255-17-1

Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Hangzhou LINGEBA Technology Co., Ltd.

Contact:+0086-571-87389059

Address:Office 1-913,NewYouth Plaza, GongShu Area, HangZhou,ZheJiang,P.R.China
Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Lian Xing Chemical Co.,Ltd.

Contact:0792-8228321

Address:10TH Floor No.121 binjiang Road Xunyang District
Hangzhou Ledun Technology Co.,Ltd.

Contact:86-571-18767088918

Address:No.6 street,XiaSha,Hangzhou,China.

Relevant to this article

Vinyl Cation Intermediates in Electrophilic Additions to Triple Bonds. 1. Chlorination of Arylacetylenes

Doi:10.1021/jo01300a023
(1980)
Synthesis of 2,5-anhydro-(β-D-glucopyranosyluronate)- and (α-L-idopyranosyluronate)-D-mannitol hexa-O-sulfonate hepta sodium salt

Doi:10.1016/j.carres.2004.03.006
(2004)
Design, synthesis, and structure-activity relationships of novel tetracyclic compounds as peripheral benzodiazepine receptor ligands

Doi:10.1016/j.bmc.2004.04.025
(2004)
Doi:10.1016/S0040-4039(01)95463-2
(1979)
In vivo assessment of newly synthesized achiral copper(ii) and zinc(ii) complexes of a benzimidazole derived scaffold as a potential analgesic, antipyretic and anti-inflammatory

Doi:10.1039/c5ra25071d
(2016)
Aminomethyl and aminoacetyl complexes of palladium(II), platinum(II), iron(II) and rhenium(I) with N-phthaloyl as amino protecting group and mechanistic studies on the palladium-catalyzed amidocarbonylation

Doi:10.1002/ejic.200300617
(2004)

Article Doi