Asymmetric Reduction of Acylstannanes. Preparation of Enantiomerically Enriched α-Alkoxystannanes

DOI: 10.1021/jo00258a048

Source and publish data:

Journal of Organic Chemistry p. 5584 - 5586 (1988)

Update date:2022-08-16

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Authors:

Chan, Philip C.-M.

Chong, J. Michael

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Article abstract of DOI:10.1021/jo00258a048

Reduction of acylstannanes (5) with BINAL-H reagents affords α-hydroxystannanes in reasonable chemical (45-69percent) and consistently good optical (up to 96percent ee) yields with predictable stereochemistry.

Full text of DOI:10.1021/jo00258a048

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