Neighboring-Group Participation in the Gas Phase. Loss of Benzaldehyde from dialkylsilyl-Substituted 1,3-Dithianes

DOI: 10.1002/hlca.19950780719

Source and publish data:

Helvetica Chimica Acta p. 1855 - 1862 (1995)

Update date:2022-08-28

Topics:

Authors:

Faessler, Juerg

Huber, Priska

Bratovanov, Svetoslav

Bigler, Laurent

Bild, Norbert

Bienz, Stefan

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Article abstract of DOI:10.1002/hlca.19950780719

<(Benzyloxy)methyl>dialkylsilyl-substituted 1,3-dithianes show in CI-MS an abundant loss of benzaldehyde from the (1+) quasi-molecular ion.The fragmentation is explained with an intramolecular redox process, where a hydride is proposed to be transfer

Full text of DOI:10.1002/hlca.19950780719

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