Russian Chemical Bulletin p. 372 - 373 (1995)
Update date:2022-08-11
Topics:
Vedeneev, V. I.
Arutyunov, V. S.
Basevich, V. Ya.
A kinetic simulation of the initiated condensation of methane in the gas phase showed that the additional generation of methyl radicals via the reaction CH4 + I2 -> CH3 + HO2 causes a nearly tenfold increase in the C2 hydrocarbon yield.However, a kinetic limit of the yield exist that is close to that determined in experiments on the catalytic oxidative condensation of methane. - Key words: kinetic simulation; oxidative condensation of methane.
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