Journal of the American Chemical Society p. 98 - 100 (1987)
Update date:2022-08-30
Topics:
Lebrilla, Carlito B.
Schulze, Christian
Schwarz, Helmut
The gas-phase reaction of bare Fe+ atoms with linear alkyl nitriles generates end-on complexes (1) which, depending on geometrical constraints, specifically interact with remote C-H bonds.Based on chain length effect studies and the investigation of labeled precursors, a mechanism is suggested which accounts for the chemospecificity observed for the loss of H2 and C2H4 from RCN/Fe+ complexes.This mechanism does not follow the analoguos reaction of Fe+ with alkenes and alkynes but involves an initial C-H insertion of the remote CH bonds followed by a C-C insertion.
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