Inorganic Chemistry p. 410 - 414 (1965)
Update date:2022-08-10
Topics:
Kodama
Parry
The reaction between F3PBH3 and CH3NH2 gives [CH3NH]F2PBH3, [CH3NH]2FPBH3, or [CH3NH]3PBH3 depending upon the experimental conditions used. In no case was CH3NH2BH3 ever detected as a product of the methylamine reaction. On the other hand the reaction between F3PBH3 and (CH3)2NH gave good yields of (CH3)2NHBH3 under conditions comparable to those used for methylamine, and gave [(CH3)2N]F2PBH3 or [(CH3)2N]2FPBH3 under more severe conditions. Displacement reactions provide a basis for listing the above bases in order of increasing base strength using BH3 as a reference acid. The order is: F3P < (CH3NH)F2P, [(CH3)2N]F2P < N(CH3)3, NH(CH3)2 < (CH3NH)2FP, [(CH3)2N]2FP. The results are discussed.
Shanghai Balmxy Pharmaceutical Co., Ltd
Contact:0086-21-24206007
Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China
Hubei Onward Bio-Development Co., Ltd.
Contact:+86-718-8417012
Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
Nanjing Yuance Industry&Trade Co., Ltd.
website:http://www.njyuance.cn/
Contact:+86-25-85439097
Address:B1702, Aoti Bldg, No. 130, Aoti Avenue, Nanjing, China
Nanjing Fubang Chemical Co.,Ltd
Contact:+86-25-83179199
Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China
Shenzhen Sunrising Industry Co., ltd.
Contact:+86 755 86571158 / 86571159 / 86571160
Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Doi:10.1016/j.jallcom.2011.02.038
(2011)Doi:10.1021/acs.inorgchem.1c01439
(2021)Doi:10.1016/j.tetlet.2015.04.124
(2015)Doi:10.1016/S0957-4166(02)00471-8
(2002)Doi:10.1039/JS8682100261
(1868)Doi:10.1002/hlca.19750580303
(1975)
