
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 109 - 118 (1982)
Update date:2022-08-28
Topics:
Kondo, Yasuhiko
Kusabayashi, Shigekazu
Theoretical procedures for investigating rate constants and activation parameters measured in binary mixed solvents have been presented on the basis of the concept of ideal associated mixtures.In methanol+acetonitrile mixtures the behaviour of the rate constant and of activation parameters for the ethyl iodide plus bromide ion reaction were interpreted as resulting from the specific interaction of bromide ion with methanol.In methanol+NN-dimethylacetamide mixtures association complex formation between methanol and NN-dimethylacetamide makes a significant contribution to the activation parameters, and this factor must be taken into account in interpreting the observed rate behaviour.
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