Journal of The Electrochemical Society, 152 ͑1͒ C36-C41 ͑2005͒
C41
small. As the current density increases ͑the field increases͒, the
thickness of the boundary layer reduces, and the electrophoresis
effect becomes stronger even for those ions in the boundary layer. A
highly crowded current density leads to much faster plating at the
edge; hence, a thicker film is formed on the edge. These two effects
are superimposed and eventually form a rabbit-ears profile on the
microstructure. Close examination reveals that a structure with
rabbit-ears profile does not have a 90° sidewall, but it has a slope
that may correspond to the fluidic friction effect. A detailed theoret-
ical study to develop a model is in progress to explain this abnormal
behavior.
So far, only the rabbit-ears profile structure and thickness distri-
bution have been noticed and studied. The cap profiles of individual
microstructures have actually been shown in many publications but
without comment. For example, the cap-like profiles and cap-like
pillars in electroplated microstructures were shown in Ref. 1 and 18,
significantly different from those rabbit-ears profiles reported by
others. The reason for not noticing this abnormal behavior is that
most of the electroplating was conducted at a relatively high current
density, where the rabbit-ears profile dominates the microstructure
profile.
1. The uniformity and profiles of electroplated microstructures
are controlled mainly by plating current density and temperature.
Optimal conditions of 8 mA/cm2 and 60°C were obtained to fabri-
cate flat cross-sectional profile microstructures and a uniform thick-
ness distribution across a specimen.
2. Plating at a higher current density produces microstructures
with rabbit-ears shape profiles, and a narrow microstructure is much
thicker than a wide structure when plated at the same conditions.
3. Lower current density plating creates microstructures with
cap-like shape profiles, and a narrow structure is much thinner than
that of a wide microstructure when plated at the same conditions.
4. Plating temperature has a significant effect on the profiles and
the uniformity of microstructures, whereas other process parameters
have little effect on them.
5. The active area density model can be used to explain the
rabbit-ears profile, while a combination of fluidic friction and
electrophoresis is believed to be responsible for the abnormal cap-
like profile of microstructures and the thinning effect for narrow
structures.
The combination of these two models can also explain the effects
of other process parameters qualitatively. As long as the ion concen-
tration is sufficient to provide the plating reaction, the effect on the
profile of individual microstructures and the thickness distribution is
insignificant, as the profile is determined by the thickness of the
boundary layers and the degree of the current crowding. Other
causes that may be responsible for the abnormal profile include the
potential perturbation by the photoresist sidewall and the impurities
absorbed.
The thickness variation across a wafer and for microstructures
with different widths is undesirable for device applications, as it
would lead to a variation in device performance and characteristics.
For Cu plating used in complementary metal oxide semiconductors,
the problem is less critical as the Cu film on a wafer is planarized by
the chemical mechanical polishing process. However, the thickness
variation across a wafer and for microstructures with different
widths will cause problems for MEMS applications, as electroplat-
ing often is employed to construct active components in MEMS
devices without planarization. A variation in thickness for narrow
components of Ϯ20% can lead to a large variation in MEMS per-
formance. This is particularly important when the active structures
are used as mechanical components where the spring constant has a
strong dependence on the thickness of the structures.
Acknowledgment
This project was sponsored by the Cambridge-MIT Institute un-
der grant no. 059/P.
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Conclusions
The uniformity of electroplated microstructures has been inves-
tigated as a function of plating conditions. The following conclu-
sions can be drawn:
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