Journal of the Electrochemical Society p. 2285 - 2292 (1987)
Update date:2022-08-17
Topics:
Green
Ali
Boone
Davidson
Feldman
Nakahara
The authors present data on the formation and structure of CVD W films deposited by the Si reduction of WF//6. Although the great majority of CVD W films deposited for IC applications are ostensibly deposited by H//2 reduction, the Si reduction of WF//6 always occurs first, even in the presence of copious amounts of H//2. Therefore, it is the Si reduction reaction that determines the nature of W/Si interface, and, in turn, such important properties as contact resistance and leakage current. We have found that Si reduced W films deposited between 210 degree and 700 degree C are porous and discontinuous, and are probably not effective barriers to the further diffusion of WF//6. The discontinuous structure of the films provides a simple mechanism for the growth of thick W films by Si reduction; such thick films have been observed with increasing frequency as of late and have been enigmatic, because the reaction between WF//6 and Si was thought to be self-limiting.
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Doi:10.1039/jr9600001794
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